schiff base वाक्य
उदाहरण वाक्य
मोबाइल
- The aldehyde then spontaneously converts to the corresponding Schiff base, ? 1-piperideine.
- Schiff base formation confirms the biosynthesis of the " N "-methyl-? 1-pyrrolinium cation.
- Notice the schiff base loses a CO2 and adds to water.
- At this step, there must be an alpha hydrogen present to form the Schiff base.
- In 1968 RyMji Noyori developed a copper-Schiff base complex for the metal-carbenoid cyclopropanation of styrene.
- It is well known that a Schiff base is more stable than a regular imine.
- Written by Larry Gross, Paul Brickman and Steven Schiff based on the novel by Tom Rooker.
- It belongs to a class of chiral diimine ligands that are synthesized via the Schiff base condensation.
- An example where the substrate forms a Schiff base to the enzyme is in the amino acids.
- Schiff base hydrolysis yields two 3-carbon products.
- In azamacrocycle chemistry, diacetylpyridines can undergo the same Schiff base condensation with N1-( 3-aminopropyl ) propane-1, 3-diamines.
- The Schiff base, which is conjugated to the enzymes pyridinium ring is the focus of the coenzyme activity.
- Lysine 69 on ornithine decarboxylase ( ODC ) binds the cofactor pyridoxal phosphate to form a Schiff base.
- Ornithine displaces the lysine to form a Schiff base attached to ODC, which decarboxylates to form a quinoid intermediate.
- It also functions as the nucleophile during hydrolysis of the enzyme-product Schiff base, leading to the release of pyruvate.
- For this step, the Schiff base must be heated to ~ 250 �C for the ring closure to occur.
- For example, using aniline as a nucleophilic catalyst, a less populated protonated carbonyl becomes a highly populated protonated Schiff base.
- A Schiff base forms between secologanin's aldehyde-group and tryptamine s amine group, from which Glu309 deprotonates tryptamine s carbon 2.
- Lys296 is conserved in all known opsins and serves as the site for the Schiff base linkage with the chromophore.
- Figure 1 : General mechanism of acetoacetate decarboxylase, proceeding through a Schiff base intermediate and producing acetone and carbon dioxide
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